Changes

From Nordan Symposia
Jump to navigationJump to search
339 bytes removed ,  03:24, 24 January 2009
no edit summary
Line 1: Line 1:  
[[Image:lighterstill.jpg]]
 
[[Image:lighterstill.jpg]]
   −
In [[thermodynamics]], a '''phase transition''' is the transformation of a thermodynamic system from one [[phase]] to another.  
+
In [[thermodynamics]], a '''phase transition''' is the transformation of a thermodynamic system from one [[phase]] to another. At phase-transition point, physical properties may undergo abrupt change- for instance, volume of the two phases may be vastly different. As an example imagine transition of liquid water into vapour at boiling point.   
 
  −
At phase-transition point, physical properties may undergo abrupt change- for instance, volume of the two phases may be vastly different.  
  −
As an example imagine transition of liquid water into vapour at boiling point.   
   
   
 
   
In the English vernacular, the term is most commonly used to describe transitions between [[solid]], [[liquid]] and [[gas]]eous [[states of matter]], in rare cases including [[Plasma (physics)|plasma]].
+
In the English vernacular, the term is most commonly used to describe transitions between [[solid]], [[liquid]] and [[gas]]eous [[states of matter]], in rare cases including [[Plasma (physics)|plasma]]. Phase transitions happen when the [[Thermodynamic free energy|free energy]] of a system is [[analytic function|non-analytic]] for some choice of thermodynamic variables - see [[phases]]. This non-analyticity generally stems from the interactions of an extremely large number of particles in a system, and does not appear in systems that are too small.
 
  −
Phase transitions happen when the [[Thermodynamic free energy|free energy]] of a system is [[analytic function|non-analytic]] for some choice of thermodynamic variables - see [[phases]]. This non-analyticity generally stems from the interactions of an extremely large number of particles in a system, and does not appear in systems that are too small.
      
To put it simply, at phase-transition point (for instance, [[boiling point]] for water) the two phases of water - [[liquid]] and [[vapour]] have identical free energies and therefore are equally likely to exist. Below the boiling point, liquid-water is more stable state of the two. At [[boiling point]] [[liquid]] and [[vapour]] are equally stable and above boiling point [[vapour]] is more stable than liquid state of [[water]].
 
To put it simply, at phase-transition point (for instance, [[boiling point]] for water) the two phases of water - [[liquid]] and [[vapour]] have identical free energies and therefore are equally likely to exist. Below the boiling point, liquid-water is more stable state of the two. At [[boiling point]] [[liquid]] and [[vapour]] are equally stable and above boiling point [[vapour]] is more stable than liquid state of [[water]].
  −
It is sometimes possible to change the state of a system non-[[adiabatic]]ally in such a way that it can be brought past a phase transition point without undergoing a phase transition. The resulting state is [[metastable]] i.e. not theoretically stable, but quasistable. See [[superheating]], [[supercooling]] and [[supersaturation]].
  −
   
== Magnetic phases ==
 
== Magnetic phases ==
 
Often also ''magnetic'' phases are used as the basis of a theory, and for introductory motivation. However, usually these are similar to the  well-known liquid (ferromagnetic) or gaseous  paramagnetic) phases, as can be seen by the two equivalent interpretations, the ''magnetic'' one ("up" or "down" spins) or the ''lattice-gas'' interpretation ("occupied" or "unoccupied" sites) of a prominent binary model, the [[Ising model]].  
 
Often also ''magnetic'' phases are used as the basis of a theory, and for introductory motivation. However, usually these are similar to the  well-known liquid (ferromagnetic) or gaseous  paramagnetic) phases, as can be seen by the two equivalent interpretations, the ''magnetic'' one ("up" or "down" spins) or the ''lattice-gas'' interpretation ("occupied" or "unoccupied" sites) of a prominent binary model, the [[Ising model]].  

Navigation menu